Step 1: Sprinkle sugar and coffee on a plate. Dip rim of cocktail glass in a bowl of water to moisten then in the sugar and coffee. Stand glass upright to let set.
Step 2: In a mixing glass or tumbler fill with ice three-fourths of the way up. Pour vodka, Kahlua, and liqueur in glass and stir until condensation forms.
Step 3: Carefully drizzle chocolate syrup on inside of prepared martini glass if desired. Strain vodka mixture into glass and serve immediately.
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