Step 1: Preheat broiler to high.
Step 2: Line a rimmed cookie sheet with foil.
Step 3: On the cookie sheet toss broccoli with 1 1/2 tablespoons oil, spreading the broccoli in an even layer. broil, stirring once until charred (10 minutes). Transfer to a serving dish.
Step 4: In a skillet over low heat and 1 1/2 tablespoons oil along with the garlic and red pepper flakes and cook stirring until garlic is browned and fragrant (3-5 minutes). Remove from heat and stir in the vinegar and salt if desired. Drizzle over the broccoli and toss.
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