Step 1: Whisk chile, garlic, pepper, lime juice, and 2 tablespoons oil in a large bowl. Add shrimp and toss to coat; season with salt. Thread shrimp onto sets of 2 skewers.
Step 2: Prepare a grill for medium-high heat; clean grates well then oil. Grill shrimp, tuning once, until cooked through and lightly charred, about 5 minutes total. Serve with lime wedges dipped in chili powder.
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