Step 1: Position rack in bottom third of your oven. Preheat to 450 degrees F. Coat a rimmed baking sheet with cooking spray (or use non-stick foil).
Step 2: Cut the orange in half and slice 1/4 inch slices (to form semi-circle slices). Toss in a large bowl with the green beans, onion, olives, oil, wine, salt and 1/4 t. pepper. Spread the mixture in an even layer on the prepared pan. Toss chicken with za'atar in the bowl, then place on top of the green bean mixture.
Step 3: Roast on the bottom rack until the green beans are tender and the chicken is no longer pink in the middle, about 15 minutes.
Step 4: Meanwhile, add broth, remaining 1/4 t pepper to a medium saucepan. Bring to a boil. Stir in couscous. Remove from heat, cover and let stand for 5 minutes. Fluff with a fork. Serve with the chicken and veggies.
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