Step 1: Heat oven to 400°F. Line a baking sheet with parchment paper.
Step 2: Remove frozen Brussels sprouts from the freezer and let them sit for a few minutes to thaw slightly.
Step 3: Add balsamic vinegar and maple syrup to a large bowl and stir to combine.
Step 4: Cut Brussels sprouts in half, discarding any loose outer leaves, and add to vinegar and syrup mixture. Stir until Brussels sprouts are evenly coated.
Step 5: Spread the Brussels sprouts out in a single layer on prepared baking sheet. Pour any remaining vinegar/syrup mixture over Brussels sprouts. Sprinkle with salt and pepper.
Step 6: Roast in oven for 20 minutes or until Brussel sprouts are golden brown.
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