Step 1: Add potatoes to pot of cold, salted water. Set over high heat, bring to a boil and cook until tender, 20-25 minutes.
Step 2: Drain well, and transfer to mixing bowl. Sprinkle 2 tablespoons vinegar and chicken stock over potatoes and toss. Transfer to refrigerator and chill 30 minutes, until liquid has been absorbed.
Step 3: In small mixing bowl, whisk together remaining 2 tablespoons vinegar, Dijon mustard, salt, pepper, olive oil and shallot. Add dressing to potatoes and toss. Add herbs and toss again. Season with additional salt and pepper, to taste, and serve.
Step 4: Refrigerate any leftovers.
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