Step 1: Beat first 6 ingredients in a large bowl at medium speed with an electric mixer until blended.
Step 2: Stir in buttermilk.
Step 3: Stir together 1 cup hot water and baking soda; stir into batter.
Step 4: Stir in vanilla.
Step 5: Pour into 2 greased and floured 9-inch round cakepans.
Step 6: Bake at 350° for 30 to 40 minutes or until a wooden pick inserted in center comes out clean.
Step 7: Cool in pans on wire racks 10 minutes; remove from pans, and cool completely on wire racks.
Step 8: Freeze layers 30 minutes.
Step 9: Cut each layer into 8 wedges.
Step 10: Stir orange food coloring into 1 1/2 cups frosting.
Step 11: Stir yellow food coloring into 1 1/4 cups frosting.
Step 12: Pipe frosting on top and sides of cake wedges to resemble candy corn.
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