Step 1: Preheat oven to 400F. Coat a 13 x 9-inch baking dish with nonstick cooking spray.
Step 2: Combine the tomatoes and boiling water in a small bowl; cover and let stand 10 minutes, or until tomatoes soften; drain.
Step 3: Heat oil in a large nonstick skillet over medium heat. Add the tomatoes, leek, mushrooms, garlic and fennel; saute 5 minutes.
Step 4: Combine the mushroom mixture, orzo, tomato juice, basil, vinegar, paprika and pepper in a large bowl; stir well.
Step 5: Spoon mixture into prepared baking dish. Bake, uncovered, for 25 minutes.
Step 6: Sprinkle provolone and Parmesan over casserole, and bake an additional 5 minutes.
Step 7: Serve hot.
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