Step 1: Preheat oven to 425°F.
Step 2: Line a large baking sheet with aluminum foil and brush it lightly with olive oil.
Step 3: Place peppers on foil, skin side up.
Step 4: Brush with additional oil.
Step 5: Bake until peppers are tender and blistered in places, 20 minutes for Italian peppers, 25-30 minutes for bell peppers.
Step 6: Meanwhile, heat garlic in the remaining 1/3 cup oil in a small skillet over low heat, about 2 minutes.
Step 7: Increase heat to medium and cook, stirring, until garlic just begins to brown and crisp, 2-3 minutes.
Step 8: Remove garlic with a slotted spoon and set aside.
Step 9: Reserve the oil in which the garlic was cooked.
Step 10: When peppers are done, transfer to a bowl, cover, and let stand 15 minutes, then peel. Italian peppers may not need to be peeled.
Step 11: Arrange peppers on a serving plate.
Step 12: Drizzle with vinegar and reserved garlic oil.
Step 13: Sprinkle with sea salt and scatter the garlic chips on top.
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