Step 1: Preheat oven to 425F.
Step 2: Combine 1 tablespoon oil, 1 1/2 teaspoons lemon zest, lemon juice, 1/4 teaspoon salt, 1/4 teaspoon black pepper, minced garlic and red pepper flakes in a medium bowl. Add shrimp; toss to combine.
Step 3: Microwave broccoli florets for 1-2 minutes (depending on your microwave wattage). Immediately arrange broccoli florets in a single layer on a rimmed jelly-roll pan coated with cooking spray.
Step 4: Arrange shrimp among the broccoli florets already in a single layer on the rimmed pan.
Step 5: Roast at 425F for 8 minutes, or until shrimp is done.
Step 6: While shrimp and broccoli are roasting, combine 1 tablespoon oil, remaining 1 1/2 teaspoons zest, remaining 1/2 teaspoon salt, and remaining 1/4 teaspoon black pepper in a large bowl. Add roasted broccoli and shrimp; toss to combine.
Step 7: Serve immediately with optional lemon wedges.
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