Step 1: Preheat oven to 400°F.
Step 2: Sprinkle pork chops with salt and pepper. Heat oil in a large ovenproof skillet over high heat. Add the pork chops and cook until brown, 2 minutes per side. Transfer to a plate.
Step 3: Add onion and cook, stirring, until softened, 3 to 4 minutes. Stir in garlic and cook, stirring, until fragrant, 30 seconds. Add orange juice and cook until most of the liquid has evaporated, 30 seconds to 1 minute. Stir in barbecue sauce. Return the pork chops to the pan, turning several times to coat with the sauce.
Step 4: Transfer the pan to the oven and bake until the pork chops are barely pink in the middle and an instant-read thermometer registers 145°F, 25-30 minutes.
Step 5: Serve the sauce over the pork chops.
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