Step 1: Preheat oven to 350°F. Coat an 8-inch square baking pan with cooking spray.
Step 2: Cream butter and sugar until light and fluffy. Add unbeaten egg and vanilla, mix well.
Step 3: Sift flour, baking powder, cocoa and instant coffee. Add to the creamed mixture alternately with the milk.
Step 4: Spread mixture evenly into the prepared baking pan.
Step 5: *TO PREPARE TOPPING:* Mix together the sugar, instant coffee and cocoa. Sprinkle evenly over the batter. Carefully pour the hot water over the top (do not stir).
Step 6: Bake for 30-35 minutes. The sauce will be on the bottom and the cake on top. Spoon out some cake and sauce into serving bowls.
Step 7: Best served hot or warm.
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